INTRODUCTION TO HYDROGEN PEROXIDE

physical and chemical properties - summary


Hydrogen Peroxide (H2O2) solutions are clear, colorless, water-like in appearance, and can be mixed with water in any proportion. At high concentrations, it has a slightly pungent or acidic odor.

H2O2 has a molecular weight of 34.02 and is nonflammable at any concentration. Its Chemical Abstracts Service Registry Number is 7722-84-1. Other physical and chemical properties of the two standard industrial strengths follow.


H2O2 Concentration 35% 50%
Active oxygen content, wt.% 16.5 23.5
Density @ 68°:
Specific gravity
lbs per gallon
gms-100% per mL

1.132
9.45
0.397

1.196
9.98
0.598
Apparent pH 2-3 1-2
Acidity, mg/L (as H2SO4) < 50 < 50
Total heavy metals, mg/L < 1 < 1
Freezing point, ° -27 -62
Boiling point, ° 226 237
Vapor pressure @ 86°, mm Hg 23 18
Viscosity:
@ 32°, cp
@ 68°, cp

1.81
1.11

1.87
1.17
Heat of decomposition, cal/gm 233 335
Mole fraction 0.22 0.346





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